ウエノ　サトシ   上野 聡    所属   工学部 応用化学科    職種   准教授
言語種別	英語
発行・発表の年月	2023/10
形態種別	学術論文
査読	査読あり
標題	Synthesis of β-Enaminones via Palladium-Catalyzed Dehydrogeantive β-Amination of Saturated Ketones
執筆形態	共著
掲載誌名	Chemistry Letters
掲載区分	国内
出版社・発行元	Chemical Society of Japan
巻・号・頁	10(52),pp.783-787
総ページ数	5
担当区分	筆頭著者,責任著者
著者・共著者	Satoshi Ueno, Shohei Yasuoka, Ryo Minamikawa, Ryoichi Kuwano
概要	A palladium-catalyzed method was developed for the synthesis of β-enaminones from saturated ketones using allyl acetate. In this reaction, allyl acetate acts as a hydrogen scavenger to α,β-dehydrogenate saturated ketones in the presence of a palladium catalyst and diamine ligand. This reaction achieved internal β-carbon–nitrogen bond formation for the first time via the dehydrogenation/conjugate addition protocol, eliminating the need to isolate unstable α,β-unsaturated ketones generated in the reaction.
外部リンクURL	https://www.journal.csj.jp/doi/10.1246/cl.230296